Lerryn's Cafe & Bar on 200 Rye Lane. It's just so super cool! It's a pastel themed, bohemian wonderland. It has a great sized garden for when the sun's out too. It does some mean sarnies and coffee by day, seasonal boozy concoctions by night. Local DJ's rock the joint from time to time.
Old Spike Roastery on 54 Peckham Rye. Now this one's extra special. Not only does Old Spike roast their own coffee beans, it's also a non profit social enterprise which provides housing and jobs for the homeless. It's only open on the weekends but I've been told that may change. The staff are darlings and happy to answer all your coffee queries!